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Champ
- Age: 23
- Height: 6' 8"
- Weight: 225 lbs.
- Home: Houston
- Occupation: Scoring touchdowns for the Players
- Favorite Saying: Pay Dirt!, Get off me!
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Dusty
- Age: 22
- Height: 5' 6"
- Weight: 110 lbs.
- Home: Temple
- Occupation: Team leader in dropped passes for the Smokers
- Favorite Saying: I’m (cough, cough) open!!
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Thomas
- Age: 12
- Home: Giddings
- Hobbies: Playing video games, going to movies, downloading music
- Favorite Saying: Comeback baby, right here.
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Angela
- Age: 11
- Home: San Antonio
- Hobbies: Schooling everyone in video games, playing basketball
- Favorite Saying: Replay that!
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Doc Duck
- Age: 16
- Height: 3' 4"
- Weight: 80 lbs.
- Home: DUCK Mission Control
- Occupation: Designed DUCK Mission Control and keeps it up and running
- Favorite Saying: The DOC don't lie; It's time to ditch the lab coat and bust out with the bling!
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Sci-Fi Duck
- Age: 15
- Height: 3' 0"
- Weight: 140 lbs. of pure muscle
- Home: DUCK Mission Control
- Occupation: DOC Duck's assistant
- Favorite Saying: Sci-Fi's da bomb, yo.
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Jimmy
- Age: 13
- Home: Houston
- Hobbies: Football and playing his PS2
- Favorite Saying: If you smoke to be cool, then you're acting like a fool.
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Ashli
- Age: 14
- Home: Arlington
- Hobbies: Going to the movies
- Favorite Saying: Tobacco is Foul!
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Jen
- Age: 12
- Home: Austin
- Hobbies: Instant messaging
- Favorite Saying: Sweet!
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Jessica
- Age: 13
- Home: Houston
- Hobbies: Downloading music
- Favorite Saying: Seriously?
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Smoke
- Age: 18
- Height: 5' 7"
- Weight: 125 lbs.
- Home: Odessa
- Occupation: Unemployed right now because she took too many smoke breaks
- Favorite Saying: Bring it on, Bad Boy!
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Chew
- Age: 19
- Height: 5' 6"
- Weight: 155 lbs.
- Home: Midland
- Occupation: Rodeo Clown
- Favorite Saying: Ladies first!
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Junior
- Age: 9
- Home: Waco
- Hobbies: Playing football
- Favorite Saying: The DUCK don't lie.
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Bobby
- Age: 10
- Home: Waco
- Hobbies: Playing video games
- Favorite Saying: The DUCK don't lie.
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Clarissa
- Age: 15
- Home: Houston
- Hobbies: Listening to music
- Favorite Saying: Duh!
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Chanel
- Age: 16
- Home: Houston
- Hobbies: Dancing with her girlfriends
- Favorite Saying: Get OUT!
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Zach
- Age: 16
- Home: Houston
- Hobbies: Washing police cars as part of his community service
- Favorite Saying: But Mom, I just got ungrounded.
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Ricky
- Age: 14
- Home: Houston
- Hobbies: Hanging out with the gang
- Favorite Saying: Naw, I'm cool.
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Slim Shakey
- Age: 21
- Home: San Angelo
- Occupation: Pizza delivery guy
- Favorite Saying: Gotta light?
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Lesley
- Age: 16
- Home: Plano
- Hobbies: Skateboarding
- Favorite Saying: You've got to be kidding!
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Jenny
- Age: 17
- Home: Plano
- Hobbies: Shopping
- Favorite Saying: Tobacco's really gross!
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Rat
- Age: 2 1/2 (human years)
- Height: 4 inches
- Weight: 8 ounces
- Home: School wall
- Occupation: Professional cheese eater
- Favorite Saying: Pass the cheese, please.
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Mutant Rat
- Age: 2 1/2 (human years)
- Height: 7 feet
- Weight: 300 lbs.
- Home: Tobacco Company Laboratory
- Occupation: Tobacco Tester
- Favorite Saying: To look like me, smoke tobacco.